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Table 1 Preparation and swelling ratios of poly(AN-co-MAA-co-NIPAM), poly(AN-co-MAA) and poly(AN-co-NIPAM) copolymers

From: Preparation and investigation of hydrolyzed polyacrylonitrile as a preliminary biomedical hydrogel

 

Molar ratio (%) (AN-MAA-NIPAM)

Molar ratio (%) (AN-MAA-NIPAM)a

Mw

Yield (%)

Swelling ratio (%)

Solubility (mg/mL)

P(AN-MAA-NIPAM)

50:25:25

47:23:30

2 000

89

65

12

25:50:25

25:52:23

2 000

61

72

14

25:25:50

22:24:54

2 000

90

81

21

50:25:25

49:26:25

20 000

82

62

5

50:25:25

47:24:29

50 000

62

58

~1

P(AN-MAA)

50:50:0

53:47:0

2 000

93

60

10

P(AN-NIPAM)

50:0:50

46:0:54

2 000

94

68

17

  1. aDetermined by 13C-NMR