Table 1 Summary of electrochemical deposition of MOF thin films and their various applications
MOF | Substrate | Electrodeposition Method | Solvent | Electrolyte | Application | Ref |
|---|---|---|---|---|---|---|
Cu -based MOF (MOF-199) | Nickel foam | Anodic | DMF | tributylmethylammonium methyl sulfate (MTBS) | Hydrogen production | [254] |
Cu-BTC (MOF-199) | Copper plate | Anodic | H2O/ethanol | [C8mim][Cl], [C12mim][Cl] | Detection of ethanol and methanol vapors | [255] |
Cu3(BTC)2 | Copper plate | Anodic | H2O/ethanol | NaBH4 | reduction of p-nitrophenol to p-aminophenol | [256] |
Cu -based MOF | Copper plate | Anodic | H2O/ethanol | phosphotungstic acid (PTA) | Detection of bromate | [257] |
Zn-BTC | Zinc plate | Anodic | Ethanol | 1,3,5-benzenetricarboxylic acid | Detection of nitro explosives | [258] |
HKUST-1 | Copper plate | Anodic | H2O/ethanol | 1-methyl-3-octylimidazolium chloride | humidity measurement | [259] |
HKUST-1 | Copper plate | Anodic | water | H2SO4, phosphate buffer 6 (PBS6) and NaOH solutions | Oxygen reduction | [260] |
HKUST-1 | Cu rod | Anodic | water | - | Catalytic hydrolysis of carbonyl sulfide | [261] |
NiBTC | Ni foam | Anodic | Ethanol | HCl solution | Hydrogen Evolution | [262] |
MIL-53(Al) | Al plate | Anodic | - | - | Conversion of methane to methanol | [263] |
MOF-5 | Zn tablet | Anodic | - | - | hydrogen evolution reaction | [264] |
Gd-BTC | Gd foil | Anodic | - | - | Detection of 2,4-dinitrotoluene | [265] |
Cu-BTEC | Poly ortho aminopheno | Cathodic | DMF | Tetrabutylammonium tetrafluroborat (TBTA)) | Capacitors | [266] |
Cu-TDPAT @CCQDs | Nickel foil | Cathodic | - | - | Determine tyrosine | [267] |
Fe/Ni-BTC | Nickel foam | Cathodic | DMF | KOH | Oxygen evolution | [268] |
Ni-BDC-NH3 /CCQDs | Copper foam | Cathodic | DMF | 2-aminoter-ephthalic acid | Detection of penicillamine | [269] |
Zn-BTC | Zinc plate | Electrophoretic | DMF | ionic liquids | Reduction of CO2 to CH4 | [270] |
Ln@UiO-66 | FTO | Electrophoretic | H2O/ethanol | CH2Cl2 | Detection of temperature | [271] |
UiO-66/C-QDs | Zinc plates | Electrophoretic | Water, ethanol, and acetone | CH2Cl2 solution | Detection of temperature | [272] |
MIL-100 (Fe) | platinum foil | Electrophoretic | Water | Li2SO4, Na2SO4, K2SO4, Cs2SO4, MgSO4, potassium acetate, and KNO3 | Supercapacitor | [273] |